Coverage-Dependent Rate-Driving Force Relationships: Hydrogen Transfer from Cerium Oxide Nanoparticle Colloids

Rishi G Agarwal1, James M Mayer1

  • 1Department of Chemistry, Yale University, New Haven, Connecticut06520-8107, United States.

Summary

This study measured hydrogen atom transfer rates on nanoceria, revealing linear Brønsted-Evans-Polanyi relationships. The findings challenge assumptions about adsorbate coverage effects in catalysis and electrocatalysis.

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