Robust polystyrene resin-supported nano-CoFe₂O₄ mediated peroxymonosulfate activation for efficient oxidation of...

Nanosized spinel cobalt ferrite (CoFe₂O₄) shows high performance in peroxymonosulfate (PMS) activation for decontamination in water, but is yet challenged by the easily leached Co(II) with high toxicity. Herein, macroporous polystyrene resin is used as the support to improve the stability of CoFe₂O₄ nanoparticles during PMS activation. CoFe₂O₄@S201 exerted high catalytic activity toward PMS activation for oxidation of 1-hydroxyethane 1,1-diphosphonic acid (HEDP), with the apparent rate normalized by Co content 38.2 times higher than that of the unsupported CoFe₂O₄. Meanwhile, one order of magnitude lower Co leaching (< 2.1 μg L^-1) was detected during the catalytic oxidation. The Co(II)-PMS complex was the primary oxidant responsible for the oxidation of HEDP. The catalytic durability and stability of CoFe₂O₄@S201 for degradation of HEDP in actual wastewater were systematically evaluated in both batch and continuous-flow mode. It is found that the organic resin, which is often considered to be intolerant to oxidation, is rather stable during the non-radical process. The total cobalt leaching of the fresh CoFe₂O₄@S201 cannot be ignored in the 100-h continuous-flow run. In contrast, much lower cobalt leaching and slightly higher oxidation efficiency were observed for the regenerated CoFe₂O₄@S201, which might be due to the removal of unreactive and unstable Co sites on the surface in the first trial. The findings shed light on the potential of organic supports for improving the stability and activity of nanosized CoFe₂O₄ and other nano-catalysts toward practical application.