Joining Two Switches in One Nano-Object: Photoacidity and Photoisomerization in Electrostatic Self-Assembly
Alexander Zika1, Mohit Agarwal1,2, Ralf Schweins2
1Department of Chemistry and Pharmacy &, Interdisciplinary Center for Molecular Materials, Friedrich-Alexander Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058, Erlangen, Germany.
Abstract:
Multi-switchable supramolecular nano-objects that respond to irradiation of different wavelengths with changes in size and shape have been built from two different water-soluble molecular switches, joined by attachment to the same polyelectrolyte. Accordingly, two wavelength-specific reactions, namely the excited-state proton dissociation of a photoacid and the cis-trans isomerization of an azo dye, are combined in one supramolecular nano-object that is stable in aqueous solution. The concept has potential in the fields of sensors, molecular motors, and transport.
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