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![[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Di-μ-chlorido-bis-[(2,2':6',2''-terpyridine-κ3 N,N',N'')copper(II)] bis-(tri-fluoro-methane-sulfonate)
Rafael A Adrian1, Jose J Duarte1, Hadi D Arman2
1Department of Chemistry and Biochemistry, University of the Incarnate Word, San Antonio TX 78209, USA.
Abstract:
In the centrosymmetric title complex, [Cu2Cl2(C15H11N3)2](CF3O3S)2, the CuII metal center is fivefold coordinated by two chloride ions and three nitro-gen atoms of the terpyridine ligand in a distorted square-pyramidal geometry; two tri-fluoro-methane-sulfonate ions complete the outer coordination sphere. π-π stacking inter-actions between the pyridyl rings in adjacent mol-ecules contribute to the alignment of the complexes in columns along the a-axis. This structure represents the first example of a binuclear dication of formula [Cu(terpy)2Cl2]2+ with tri-fluoro-methane-sulfonate as counter-ions.
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