Increased diurnal difference of NO₂ concentrations and its impact on recent ozone pollution in eastern China in...

Nitrogen dioxide (NO₂) is a key tropospheric O₃ precursor. Since 2013, efforts to decrease air pollution in China have driven substantial declines in annual NO₂ concentrations, whereas ozone (O₃) concentrations have increased. Based on nationwide NO₂ observations and a regional air quality model (WRF-CMAQ), we analyzed trends in the diurnal difference (DD, the difference between nighttime and daytime concentrations) of NO₂ concentrations across eastern China and in five national urban agglomerations (UAs) from 2014 to 2021, and explored the factors underlying such changes and the potential impacts on O₃ pollution. We found that the observed DD of NO₂ has increased in most cities and UAs, and that this trend can be primarily attributed to changes in anthropogenic emissions, based on comparison with DDs simulated with fixed anthropogenic emissions, which generally showed much weaker trends and little interannual variation. A sensitivity analysis using the WRF-CMAQ model was conducted to investigate the impact of a modified diurnal cycle of nitrogen oxides (NO_x) emissions on O₃ concentrations. The result revealed that enhancing the DD of NO₂ would increase O₃ concentrations in the morning and the daily maximum 8-h O₃ concentrations in the cities with high NO_x concentrations, as well as downwind areas of cities, indicating that greater DDs in NO₂ is one of the reasons that have led to the enhanced China's O₃ pollution in recent years.