Uniform-embeddable-distributed Ni₃S₂ cocatalyst inside and outside a sheet-like ZnIn₂S₄ photocatalyst for boosting...

The rational cocatalyst design is considered a significant route to boost the solar-energy conversion efficiency for photocatalytic H₂ generation. However, the traditional cocatalyst-loading on the surface of a photocatalyst easily leads to scarce exposed active sites induced by the agglomeration of cocatalysts and a hindrance of the light absorption of the photocatalyst, thus significantly limiting the enhancement of the photocatalytic H₂-generation performance. Herein, a new concept of uniform-embeddable-distributed cocatalysts is put forward. Consequently, uniform-embeddable-distributed cocatalysts of Ni₃S₂ were designed and constructed inside and outside of the nanosheet-like ZnIn₂S₄ photocatalyst to form a Ni₃S₂/ZnIn₂S₄ binary system (UEDNiS/ZIS). The unique uniform-embeddable-distributed Ni₃S₂ cocatalyst (UEDNiS) could provide abundant exposed active sites, facilitate the spatial separation and ordered transfer of charges inside and outside of ZnIn₂S₄ nanosheets, and reduce the hydrogen-adsorption free energy for photocatalytic H₂-generation reactions. As a result, UEDNiS/ZIS exhibited a high photocatalytic H₂-generation rate of 60 μmol h^-1 under visible-light irradiation, almost 7.8 and 2.8 times higher than pristine ZnIn₂S₄ and the traditional surface-loaded Ni₃S₂/ZnIn₂S₄ (TSLNiS/ZIS), respectively. This work represents a new cocatalyst-design approach to realize high-efficiency hydrogen evolution in binary heterostructured photocatalytic systems.