Simultaneous high p-nitrophenol concentration and nitrogen removal by two-stage membrane biofilm reactor

P-nitrophenol (PNP) is highly toxic and difficult to degrade, causing great harm to the ecological environment and human health. A two-stage bench-scale membrane biofilm reactor (MBfR) was constructed to treat wastewater containing high concentration of PNP and the generated nitrogen without external organic carbon sources. The two reactors were supplied with oxygen and methane, respectively. O₂-MBfR was used for the degradation of PNP and the improvement of wastewater biodegradability. CH₄-MBfR was used for the total nitrogen (TN) removal treatment from O₂-MBfR effluent. In this experiment, the performance of the two-stage MBfR process was evaluated and optimized by adjusting operational parameters (aeration pressure, HRT, and pH). Under the optimal operation parameters, the removal efficiencies of PNP (100 mg/L) and TN attained 89.70% and 69.24%, respectively, and the removal loads were 0.930 g·m^-2·d^-1 and 241.42 mg·m^-2·d^-1, respectively. The reactor was able to accommodate the concentrations of PNP up to 200-400 mg/L, and the reactor reached maximum efficiency throughout the process when the concentration of PNP in the wastewater was 250 mg/L. The removal rates of PNP and TN reached 95.0% and 69.48%, respectively, and the removal loads were 2.37 g·m^-2·d^-1 and 96.22 mg·m^-2·d^-1, respectively. This research provides a better solution for multi-MBfR to treat toxic industrial wastewater containing phenol, nitrophenol, and further TN removal, which would not release any air pollutants into the atmosphere.