Dimethylammonium Cation-Induced 1D/3D Heterostructure for Efficient and Stable Perovskite Solar Cells

Mixed-dimensional perovskite engineering has been demonstrated as a simple and useful approach to achieving highly efficient and more-durable perovskite solar cells (PSCs), which have attracted increasing research interests worldwide. In this work, 1D/3D mixed-dimensional perovskite has been successfully obtained by introducing DMAI via a two-step deposition method. The additive DMA⁺ can facilitate the crystalline growth and form 1D DMAPbI₃ at grain boundaries of 3D perovskite, leading to improved morphology, longer charge carrier lifetime, and remarkably reduced bulk trap density for perovskite films. Meanwhile, the presence of low-dimension perovskite is able to prevent the intrusion of moisture, resulting in enhanced long-term stability. As a result, the PSCs incorporated with 1D DMAPbI₃ exhibited a first-class power conversion efficiency (PCE) of 21.43% and maintained 85% of their initial efficiency after storage under ambient conditions with ~45% RH for 1000 h.