Optimizing the Synthetic Conditions of "Green" Colloidal AgBiS₂ Nanocrystals Using a Low-Cost Sulfur Source

Colloidal AgBiS₂ nanocrystals (NCs) have attracted increasing attention as a near-infrared absorbent materials with non-toxic elements and a high absorption coefficient. In recent years, colloidal AgBiS₂ NCs have typically been synthesized via the hot injection method using hexamethyldisilathiane (TMS) as the sulfur source. However, the cost of TMS is one of the biggest obstacles to large-scale synthesis of colloidal AgBiS₂ NCs. Herein, we synthesized colloidal AgBiS₂ NCs using oleylamine@sulfur (OLA-S) solution as the sulfur source instead of TMS and optimized the synthesis conditions of colloidal AgBiS₂ NCs. By controlling the reaction injection temperature and the dosage of OLA-S, colloidal AgBiS₂ NCs with adjustable size can be synthesized. Compared with TMS-based colloidal AgBiS₂ NCs, the colloidal AgBiS₂ NCs based on OLA-S has good crystallinity and fewer defects.