Interface characteristics of graphene/ZnS hybrid-dimensional heterostructures

Graphene/ZnS hybrid-dimensional heterostructure is an excellent combination to regulate and improve the conductivity and sensitivity of components, in which the interface effects have crucial impacts on the performance of devices. In this work, we investigate the interface characteristics of Graphene/ZnS 2D/3D heterostructures. X-ray photoelectron spectra show that the ZnS binding energy shifts to lower energy by 0.3 eV after forming heterojunction with graphene. The fluorescence and absorption spectra confirm the luminescence enhancement and blue-shift of the absorbance edge of ZnS caused by graphene. The composition of Graphene/ZnS heterostructure facilitates separation and transfer of spatial charges, resulting in rapid electron transport.