Vivianite recovery from high concentration phosphorus wastewater with mine drainage as iron sources

High concentration phosphorus wastewater has attracted much attention due to the safety of water ecology and the potential crisis of phosphorus resource, which is caused by large amounts of phosphorus discharging into natural water bodies. Vivianite (Fe₃(PO₄)₂·8H₂O) crystallization has been considered as an effective technology for phosphorus recovery. In this study, we develop a potentially low-cost, sustainable approach to recover phosphorus from high concentration phosphorus wastewater using mine drainage as iron source. Inoculated with both sewage and Geobacter, mine drainage was suitable for vivianite recovery from high concentration phosphorus wastewater with PO₄^3- concentration between 6 and 18 mM. When the PO₄^3- concentration increased gradually, both phosphorus removal efficiency (R_P) and vivianite recovery efficiency (R_V) decreased significantly. The highest R_V of 48 % was obtained with 9 mM PO₄^3- in Geobacter batches (CJ2 batches), which was 15 % higher than that in the paralleled sewage batches (33 % in HJ2). Simultaneously, vivianite accounted for 91 % of the solid phosphate compounds in CJ2 batches due to the enhancement of Geobacter.