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Updated: Aug 21, 2025

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
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Fluorinated leaning pillar[6]arene: synthesis, structure and selective iodide anion binding by anion-π interactions
Weichun Li1, Peng Qin1, Xing-Xing Zhao1
1Key Laboratory of Eco-Functional Polymer Materials of the Ministry of Education, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, P. R. China. bingbingshi@nwnu.edu.cn.
Abstract:
Anion recognition has continuously attracted significant attention due to its important role in environmental and biological sciences. Here, we have designed and synthesized an electron-deficient fluorinated leaning pillar[6]arene 1 that contains two tetrafluoro-benzene units. The electron-deficient fluorinated leaning pillar[6]arene 1 is capable of selectively recognizing iodide anions to form a host-guest complex with 1 : 1 stoichiometry driven by anion-π interactions. Our work ascribes this selective recognition to the preorganization of macrocycles, suitable cavity size, and the effect of anion-π interactions. The innovative application of this macrocycle offers us a new avenue for the design of selective receptors for anions and electron-deficient macrocyclic arenes.
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