Effect of the Alkyl Chain Length on Assessment as Thermo-Responsive Draw Solutes for Forward Osmosis

A series of thermo-responsive tetrabutylphosphonium 1-alkanesulfonates (abbreviated as [P₄₄₄₄][C S], n = 6, 8, 10, and 12), where n is the number of carbon atoms in the alkyl group on the 1-alkanesulfonate anion, were prepared by an ion-exchange reaction to investigate their potential ability toward the application of draw solutes in forward osmosis (FO). We systematically studied the recovery properties and FO performance of [P₄₄₄₄][C S]. This series exhibited lower critical solution temperature (LCST) characteristics, which offer a clear advantage of being energy-efficient for recovering draw solutes; however, [P₄₄₄₄][C₆S] was only observed at 20 wt %. The LCSTs of the 20 wt % [P₄₄₄₄][C₆S], [P₄₄₄₄][C₈S], [P₄₄₄₄][C₁₀S], and [P₄₄₄₄][C₁₂S] draw solutions were approximately 83, 54, 49, and 56 °C, respectively. Moreover, when the orientation of the active layer was heading toward the draw solution (AL-DS mode), the water and reverse solute flux of [P₄₄₄₄][C₁₀S] were about 1.58 LMH and 0.81 gMH, respectively, at 20 wt % aqueous solutions. When the membrane was used in the active layer facing the feed solution (AL-FS) system, the water and reverse solute flux of [P₄₄₄₄][C₁₀S] were approximately 0.71 LMH and 0.38 gMH, respectively, at 20 wt % aqueous solutions. Thus, this study is the first to examine the structural transformations of the bulkier alkyl group on the sulfonate anion moiety and its feasibility as the new draw solute for the FO system.