Nickel hydroxide nanoflower-based dispersive solid-phase extraction of copper from water matrix

In this work, a dispersive solid-phase extraction method based on Ni(OH)₂ nanoflowers (Ni(OH)₂-NFs-DSPE) was developed to separate and preconcentrate copper ions from tap water samples for determination by flame atomic absorption spectrometry (FAAS). Ni(OH)₂-NFs was synthesized using a homogeneous precipitation technique and used as sorbent for copper preconcentration. X-ray diffraction, scanning electron microscopy, and Fourier-transform infrared spectroscopy were used to characterize the synthesized sorbent. All experimental variables were carefully optimized to achieve a high enhancement factor of 107.5-folds with respect to the detection sensitivity of the conventional FAAS. The proposed method's analytical parameters including LOD, LOQ, and linear range were determined as 1.33 μg/L, 4.42 μg/L, and 3.0-40 μg/L, respectively. To assess the applicability and reliability of the developed method, optimal conditions were applied to tap water samples and satisfactory percent recoveries (94-103%) were obtained for the samples spiked at 20 and 30 μg/L. This validated the accuracy and feasibility of the developed method to real samples. The developed method can be described as a simple, efficient, and rapid analytical approach for the accurate determination of trace copper ions in water samples.