The g-C₃N₄@CdO/ZnO ternary composite: photocatalysis, thermodynamics and acute toxicity studies

Binary and ternary nanocomposites (NCs) were synthesized by precipitation and through facile one-pot ultrasonic assisted methods to serve as photocatalysts for treatment of wastewater as well as their toxicity toward aquatic organism (Nile tilapia). The crystalline structure, band gap energy and functional groups of these materials were characterized by XRD, UV-Vis, and FT-IR instrumental techniques. Based on the UV-Vis study, the band gap of ZnO/CdO (ZC) to hybrid g-C₃N₄@ZnO/CdO (GZC) nanocomposite was reduced from 3.41 eV to 3.21 eV, suggesting good charge carrier mobility. Photocatalytic degradation performances of ZC and GZC were further assessed by conducting methyl red (MR) photodegradation reaction using UV light. The highest degradation efficiency was achieved for GZC NCs (97.78%) than ZC (89.41%) in 2 h. The values of free energy, and enthalpy were negative; showing spontaneous photodegradation of MR. The kinetics of photodegradation follows pseudo-first-order reaction with rate order of 0.0713 min^-1. The HO∗ and O₂∗ were main active species for the photodegradation of MR. The toxicity of NCs calculated and the lethal concentration (LC₅₀) was 113 ppm after 12 h.