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Scale-up Chemical Synthesis of Thermally-activated Delayed Fluorescence Emitters Based on the Dibenzothiophene-S,S-Dioxide Core
Published on: October 24, 2017
Trifluoromethylated thermally activated delayed fluorescence molecule as a versatile photocatalyst for
Tatsuya Morofuji1, Takuma Kurokawa1, Youhei Chitose2,3
1Department of Chemistry, Faculty of Science, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo 171-8588, Japan. tatsuya.morofuji@gakushuin.ac.jp.
Abstract:
In this study, we propose that the trifluoromethylated thermally activated delayed fluorescent molecule 4[Cz(CF3)2]IPN is a versatile organic photocatalyst that can be used for electron-transfer-driven reactions requiring a photocatalyst with high oxidizing power and energy-transfer-driven reactions that require an Ir photocatalyst. 4[Cz(CF3)2]IPN was used in radical reactions via electron transfer and dearomative cycloaddition reactions via energy transfer.
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