Modelling Development in Radical (Co)Polymerization of Multivinyl Monomers
Related Experiment Video
Updated: Aug 20, 2025

Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
Published on: April 22, 2016
Jing Lyu1, Yinghao Li1, Zishan Li1
1Charles Institute of Dermatology, School of Medicine, University College Dublin, Dublin, Ireland.
Abstract:
Radical polymerization (RP) of multivinyl monomers (MVMs) provides a facile solution for manipulating polymer topology and has received increasing attention due to their industrial and academic significance. Continuous efforts have been made to understand their mechanism, which is the key to regulating materials structure. Modelling techniques have become a powerful tool that can provide detailed information on polymerization kinetics which is inaccessible by experiments. Many publications have reported the combination of experiments and modelling for free radical polymerization (FRP) and reversible-deactivation radical polymerizations (RDRP) of MVMs. Herein, a minireview is presented for the most important modelling techniques and their applications in FRP/RDRP of MVMs. This review hopes to illustrate that the combination of modelling and wet experiments can be a great asset to polymer researchers and inspire new thinking for the future MVMs experiment optimization and product design.
Related Concept Videos
Radical Chain-Growth Polymerization: Mechanism
Radical Chain-Growth Polymerization: Overview
Radical Chain-Growth Polymerization: Chain Branching
Free-Radical Chain Reaction and Polymerization of Alkenes
Olefin Metathesis Polymerization: Overview
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists...
Step-Growth Polymerization: Overview
Many natural and synthetic polymers are produced by...

