Heavy metal mapping, source identification, and ecological risk assessment in the International Hamoun wetland,...

This study is aimed at assessing the ecological risk of heavy metals (HMs) in the International Hamoun wetland, southeastern Iran. Twenty sediment samples were collected from the wetland surface for geochemical analysis of 23 HMs. The inverse distance weighting (IDW) technique was used to map the HMs. The single and multi-element pollution indicators and PER index (PERI) were respectively used to determine the contamination intensity and PER level. The principal components analysis (PCA) was performed to identify the HM source. The mean concentration of cesium (Cs: 5.2 µg/g), selenium (Se: 0.9 µg/g), and tellurium (Te: 0.2 µg/g) was higher than their mean values in the Earth's crust. The enrichment factor (EF) showed the Hamoun was high to extremely enriched by Te, As, and Se. The geo-accumulation index (GeoI) revealed the highest level of contamination caused by As, barium (Ba), cobalt (Co), chromium (Cr), cuprum (Cu), ferrum (Fe), manganese (Mn), nickel (Ni), lead (Pb), rubidium(Rb), titanium (Ti), vanadium(V), yttrium (Y), and zinc (Zn) in most study sites. The sediment contamination factor in more than 55% of the sediment samples was between 8 and 16, indicating very high contamination intensity in the studied wetland. The PER values were between 80 and 160 in more than 60% of the sediment samples, suggesting a considerable risk in the wetland. The PCA showed both anthropogenic and crustal activities were effective in increasing the concentration of HMs in the wetland. The largest ecological risk was due to arsenic (As) and cadmium (Cd). It is recommended to pay more attention to these HMs, which could cause more environmental pollution in the International Hamoun wetland, southeastern Iran.