Recent research advancements in microwave photocatalytic treatment of aqueous solutions

In recent years, microwave (MW) photocatalytic treatment was used for the removal of several pollutants from wastewater to overcome the disadvantages of conventional photocatalytic treatment. MW irradiation significantly enhanced the photocatalytic degradation pollutants and is considered an innovative treatment approach. This enhancement in photoactivity was mainly attributed to thermal and non-thermal effects of the MW irradiation. Even though the thermal effects of MW irradiation have been conclusively studied, there are many conflicting results regarding the non-thermal effects in catalysts. In general, it has been verified that the non-thermal effects are due to the electrical and magnetic properties of MW. In this article, a detailed review of the recent advancements in MW-assisted photocatalysis has been done, emphasizing the non-thermal effects of MW radiation on the surface of the catalysts. Also, the evolution of external ultraviolet (UV) sources from the conventional Hg lamp to the latest microwave-driven electrodeless lamps (MDEL) has been discussed. MW photocatalytic treatment using MDELs showed complete removal of lignin, dimethyl phthalate (DMP), and azo dye reactive brilliant red X-3B (BR) and more than 90% removal for cimetidine (CMT), rhodamine B (RB), and methylene blue (MB). A brief comparison regarding the removal efficiencies of pollutants by various AOPs and MW photocatalysis has been made to understand the enhanced photoactivity. In addition, various operating parameters that affect the MW photocatalysis like MW intensity, pH, dissolved oxygen, and catalyst dosage; the degradation pathways of various pollutants; and the cost assessment of MW photocatalysis are discussed in detail. This paper will deliver a scientific and technical overview and useful information to scientists and engineers working in this field.