Fluorimetric Recognition of Nerve Agent Mimic Diethylchlorophosphate Along with Cu²⁺/Hg²⁺ Ions Using Imidazole...

An imidazole possessing sensor (1) has been designed and developed by simple one step reaction and characterization was done by using common spectroscopic methods. The fluorimetric sensing of nerve agent mimic, DCP, was carried out by observing blue shift in spectra accompanied with quenching in semi-aqueous solvent. The sensor was found proficient for the detection of DCP amongst other phosphates with detection limit of 69 nM. Furthermore, upon incorporation of various metal ions to CH₃CN:H₂O (4:1, v/v) solution of 1 (λ_ex 340 nm), the fluorescent probe turned non-fluorescent only in presence of Cu²⁺/Hg²⁺ ions. This was accompanied by fluorescent color change from light blue to yellow in case of Hg²⁺ and colorless in case of Cu²⁺ ions. Moreover, practical applications of sensor 1 were investigated for recognition of Cu²⁺ and Hg²⁺ ions in real water samples along with the detection of DCP in soil samples from different areas. Differential emission changes observed with addition of Hg²⁺ ions and DCP led to observation of "NOR" and an "INHIBIT" molecular photonic logic operations at 446 and 385 nm, respectively.