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Updated: Aug 19, 2025
Application of a Coupling Agent to Improve the Dielectric Properties of Polymer-Based Nanocomposites
Published on: September 19, 2020
Effect of Carbon Dots Concentration on Electrical and Optical Properties of Their Composites with a Conducting
Grigorii V Nenashev1, Maria S Istomina2,3, Roman S Kryukov2
1Ioffe Institute, 26 Politekhnicheskaya, 194021 Saint Petersburg, Russia.
Cqd/Pedot:
PSS composites were prepared via the hydrothermal method from glucose carbon quantum dots (CQDs) and an aqueous solution of PEDOT:PSS conducting polymer and their electrical and optical properties were investigated. The morphology and structure of these samples were investigated by AFM, SEM, EDX, and EBSD. It was found that the CQDs and CQD/PEDOT:PSS composites had a globular structure with globule sizes of ~50-300 nm depending on the concentration of PEDOT:PSS in these composites. The temperature dependence of the resistivity was obtained for the CQD/PEDOT:PSS (3%, 5%, 50%) composites, which had a weak activation character. The charge transport mechanism was discussed. The dependence of the resistivity on the storage time of the CQD/PEDOT:PSS (3%, 5%, 50%) composites and pure PEDOT:PSS was obtained. It was noted that mixing CQDs with PEDOT:PSS allowed us to obtain better electrical and optical properties than pure CQDs.
Cqd/Pedot:
PSS (3%, 5%, 50%) composites are more conductive composites than pure CQDs, and the absorbance spectra of CQD/PEDOT:PSS composites are a synergistic effect of interaction between CQDs and PEDOT:PSS. We also note the better stability of the CQD/PEDOT:PSS (50%) composite than the pure PEDOT:PSS film.
Cqd/Pedot:
PSS (50%) composite is promising for use as stable hole transport layers in devices of flexible organic electronics.
