Synthesis and Characterization of Novel Core-Shell ZnO@SiO₂ Nanoparticles and Application in Antibiotic and Bacteria...

A novel core-shell nanomaterial, ZnO@SiO₂, based on rice husk for antibiotic and bacteria removal, was successfully fabricated. The ZnO@SiO₂ nanoparticles were characterized by X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX), Fourier transform infrared (FTIR) spectroscopy, transmission electron microscopy (TEM), photoluminescence spectroscopy (PL), Brunauer-Emmett-Teller (BET) method, diffuse reflectance ultraviolet-vis (DR-UV-vis) spectroscopy, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, and ζ-potential measurements. β-Lactam antibiotic amoxicillin (AMX) was removed using ZnO@SiO₂ nanoparticles with an efficiency greater than 90%, while Escherichia coli removal was higher than 91%. The optimum effective conditions for AMX removal using ZnO@SiO₂, including solution pH, adsorption time, and ZnO@SiO₂ dosage, were 8, 90 min, and 25 mg/mL, respectively. The maximum adsorption capacity reached 52.1 mg/g, much higher than those for other adsorbents. Adsorption isotherms of AMX on ZnO@SiO₂ were more in accordance with the Freundlich model than the Langmuir model. The electrostatic attraction between negative species of AMX and the positively charged ZnO@SiO₂ surface induced adsorption, while the removal of E. coli was governed by both electrostatic and hydrophobic interactions. Our study demonstrates that ZnO@SiO₂ based on rice husk is a useful core-shell nanomaterial for antibiotic and bacteria removal from water.