Destabilization of Pickering emulsions by interfacial transport of mutually soluble solute

Pickering emulsions (PEs) once formed are highly stable because of very high desorption energies (∼10⁷ k_BT) associated with particles adsorbed to the interfaces. The destabilization of PEs is required in many instances for recovery of valuable chemicals, products and active compounds. We propose to exploit interfacial instabilities develop by the addition of different types of solutes to PEs as a route to engineer their destabilization.

PEs stabilized by (i) spherical particles, (ii) non-spherical particles, (iii) oppositely charged particle-particle mixtures, and (iv) oppositely charged particle-polyelectrolyte mixtures are formulated. Different types of solutes are added to these highly stable PEs and the macroscopic as well as microscopic changes induced in the PEs is recorded by visual observation and bright field optical microscopy.

Our results point to a simple yet robust method to induce destabilization of PEs by transiently perturbing the oil-water interface by transport of a mutually soluble solute across the interface. The generality of the method is demonstrated for different kind of solutes and stabilizers including particles of different sizes (nm to µm), shapes (sphere, spheroids, spherocylinders) and types (polystyrene, metal oxides). The method works for both oil-in-water (o/w) and water-in-oil (w/o) PEs with different kinds of non-polar solvents as oil-phase. However, the method fails when the solute is insoluble in one of the phases of PEs. The study opens up a new approach to destabilization of particle stabilized emulsions.