Related Experiment Video
Updated: Aug 19, 2025

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
Published on: October 18, 2019
Diphenylsilylsilanolates Enable the Transfer of a Wide Range of Silyl Groups
Hiroki Yamagishi1, Fuyuki Harata1, Jun Shimokawa1
1Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto, 606-8502, Japan.
Abstract:
Development of silylating reagents that can transfer a wide range of silyl groups has been a long-standing challenge. Herein we report sodium diphenylsilylsilanolates as new stable and handy silylating reagents that could be synthesized from chlorosilanes. The new reagents retain the ability of dimethylsilylsilanolates for the delivery of a variety of silyl groups in palladium-catalyzed silylation of aryl bromides irrespective of the steric and electronic properties of silyl groups to be transferred.
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