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Updated: Aug 19, 2025

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Substitution pattern in ruthenium octa-n-butoxyphthalocyanine complexes influence their reactivity in N-H carbene
Andrey P Kroitor1,2, Alexander A Dmitrienko3, Alexander G Martynov2
1Institut de recherches sur la catalyse et l'environnement de Lyon (IRCELYON), UMR 5256, CNRS - Université Lyon 1, 2 av. A. Einstein, 69626 Villeurbanne, France. alexander.sorokin@ircelyon.univ-lyon1.fr.
Abstract:
Ruthenium phthalocyanine complexes bearing n-OBu substituents in the peripheral or non-peripheral positions are efficient catalysts for the selective double or single carbene insertion to the amine N-H bonds. This complementary reactivity of two Ru complexes can be used for the synthesis of asymmetric tertiary amines and diamines bearing different substituents and has been demonstrated by two examples of readily available primary amines using different carbene precursors in successive reactions.
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