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Porous TiNi3-based intermetallics as active and robust monolith catalysts for hydrogen evolution
Yue Qiu1, Zhenli He1, Yuehui He1
1State Key Laboratory of Powder Metallurgy, Powder Metallurgy Research Institute, Central South University, Changsha 410083, China. jiangyao@csu.edu.cn.
Abstract:
Electrochemical water splitting offers an appealing method to produce hydrogen as we attempt to achieve global carbon neutrality. However, the lack of earth-abundant, low-cost, active, and stable catalysts at large current densities severely hinders its industrial applications. TiNi3-based intermetallics as porous monolith catalysts (PMCs) exhibit an efficient hydrogen evolution reaction (HER) performance (an overpotential of 244 mV to afford 200 mA cm-2) and excellent stability in 1 M KOH. Theoretical calculations demonstrate that the synergetic effect between Ni and Mo can enhance HER activity. PMCs provide a new strategy to design catalysts with efficient and stable performance for industrial applications.
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