Poly-L-aspartic acid based nonconventional luminescent biomacromolecules with efficient emission in dilute solutions...

Nonconventional luminescent macromolecules exhibiting bright fluorescence or phosphorescence emission at high concentrations and solid-state have attracted significant attention due to their promising application in different fields. However, most reported nonconventional luminescent macromolecules show weak or no emission in dilute solutions, limiting their large-scale applications. Herein, nonconventional luminescent biomacromolecules with hydrophobic rigid chains, hydrophilic flexibility and inter- or intra-molecular hydrogen bonding interactions were proposed to achieve effective luminescence in dilute solutions. Poly-L-aspartic acid (PASA) with a fluorescence quantum yield of 4.6 % in a dilute solution (0.8 mg/mL) was synthesized to validate this design strategy. The fluorescence intensity of PASA solution increased with the increase of the concentration, demonstrating a clustering-triggered emission (CTE) effect. Furthermore, the fluorescence intensity significantly enhanced when adding Al³⁺ into PASA aqueous solution via the Al³⁺ recognition effect. The detection limits for Al³⁺ (1.71 × 10^-6 mol/L) meet the World Health Organization (WHO) requirements for food detection. At last, PASA solid-state samples exhibit room temperature phosphorescence emission.