Oxoiron(IV)-dominated Heterogeneous Fenton-like Mechanism of Fe-Doped MoS₂

Oxoiron(IV) species are a critical intermediate in the Fe-based Fenton-like process at circumneutral pH, and its oxidative reactivity is closely related to the ligands. An optional inorganic host material, MoS₂ , is selected to construct a highly reactive sulfur ligand coordinated Fe species in this work. The Fe species doped in MoS₂ is presented as the Fe^II centre and triggers the transformation of the 2H phase to the octahedral 1T phase MoS₂ . The role of the interaction between doped Fe and the MoS₂ host lattice on the formation of oxoiron(IV) is studied. A significant Fenton-like reactivity and a remarkable accumulation of oxoiron(IV) species were observed for Fe-MoS₂ . The quenching experiment was implemented to disclose the predominant role of oxoiron(IV) species in the Fe-MoS₂ /H₂ O₂ Fenton-like system. Furthermore, oxoiron(IV) species could transform into the ⋅O₂ ^- and ¹ O₂ , which further expedites the Fenton-like reaction.