Novel cubical Ag(NP) decorated titanium dioxide supported bentonite thin film in the efficient removal of bisphenol A...

The persistent endocrine-disrupting chemical bisphenol A is posing serious health concerns; hence, it is known to be an emerging and potential water contaminant. The present investigation aims to synthesize novel cubical Ag(NP) decorated titanium dioxide-supported bentonite (Ag/TiO₂@Clay) nanocomposite using a novel synthetic process. The nanocomposite materials were characterized by several analytical methods viz., transmission electron microscopy (TEM), X-ray diffraction (XRD) analyses, energy-dispersive X-ray spectroscopy (EDX), atomic force microscopy (AFM), scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET) and diffuse reflectance spectroscopy (DRS). Further, the photocatalytic removal of bisphenol A was conducted utilizing the thin film catalyst under the LED (light emitting diode; visible light) and UV-A (ultra violet-A) light sources. The parametric studies solution pH (6.0-12.0), pollutant concentrations (1.0-20.0 mg/L), and the interaction of several scavengers and co-existing ions are studied extensively to demonstrate the insights of the removal mechanism. The mineralization of bisphenol A and repeated use of the thin film catalyst showed the potential usage of photocatalysts in the devised large-scale operations. Similarly, the natural matrix treatment was performed to evaluate the suitability of the process for real implications.