Bimetallic MOFs loaded cellulose as an environment friendly bioadsorbent for highly efficient tetracycline removal

Due to the increasingly serious antibiotic-related pollution, it is crucial to develop novel green bioadsorbents to effectively remove antibiotics from aqueous solutions. In this study, Fe doped zeolitic imidazolate frameworks-8 loaded cellulose (Fe/ZIF-8@cellulose) aerogels were prepared. The synthesized Fe/ZIF-8@cellulose aerogels were characterized experimentally including morphology observation and chemical compositions determination. The effects of bioadsorbent dosage, solution pH, adsorption time, initial TC concentration and adsorption temperature on the TC adsorption behaviors were systematically studied. Due to the introduction of Fe in the ZIF-8, the maximum adsorption capacity of Fe/ZIF-8@cellulose for TC could reach as high as 1359.2 mg/g, which is higher than the reported ZIF-8 loaded polysaccharide based adsorbents. The adsorption kinetics and isotherm of TC adsorption were also determined. With the cellulose as the matrix to load Fe/ZIF-8, the obtained Fe/ZIF-8@cellulose aerogels exhibited good reusability. Most importantly, the TC adsorption mechanism was proposed. The results of our finding suggest that the Fe doping into MOFs is an effective strategy to improve the antibiotics adsorption performance and the application of cellulose as the matrix is a valuable method to increase the cyclic utilization. This study highlights the potentials of applying the Fe/ZIF-8@cellulose aerogels in the antibiotics removal for practical wastewater.