Highly customized porous TiO₂-PANI nanoparticles with excellent photocatalytic efficiency for dye degradation

The present work encompasses a simple strategy to synthesize highly porous TiO₂ by incorporating PANI polymer into the sol-gel chemistry of Titanium dioxide/Titanium (IV)-iso-propoxide (TiO₂/TTIP). A series of TiO₂ samples by varying wt.% of PANI, have been synthesized. A probable growth mechanism has been presented for the formation of a porous ginger-like nanostructure of TiO₂-PANI (TP). HRTEM images reveal that the particle size range is 6-16 nm for pristine TiO₂ and 5-13 nm for TP samples. XPS analysis confirms the presence of the hydrogen bonds in-between surface hydroxyl groups (Ti-OH) of TiO₂ and the protonated nitrogen of PANI. UV-visible absorption study reveals a small shift towards longer wavelength for TP8 sample than that of pristine TiO₂ (λ_max = 314 nm) as well as reduction in E_g value from 3.02 eV to 2.89 eV. FTIR results confirm the successful interaction of PANI and TiO₂. BJH and BET analysis confirms an increase of porosity in TP8 sample with an average pore volume of 0.36 cm³ g^-1. High photocatalytic activity (98.77%) towards Methylene blue dye degradation is observed for TP8 sample having 8 wt% of PANI and it is explained through the combined effect of structural porosity of TiO₂ and synergic effect of PANI. The K_appa value at pH 11 (0.01372 min^-1) is found to be 7.84-folds higher than that of the photocatalytic reaction at pH 3 (K_appa = 0.00175 min^-1). While pristine TiO₂ exhibits the minimum removal efficiency (89.57%) with K_appa of 0.00756 min^-1. K_appa value of catalysis reaction for TP8 is found to be almost 2-fold higher than pristine TiO₂. Quantum Yield value for TP8 is found to be 3.59 × 10^-4 molecules photon^-1. This high Quantum Yield value of present photocatalytic system explicates the low energy consumption for the treatment of textile dye pollutant. Additionally, STY value (1.79 × 10^-5 molecules photon^-1 mg^-1) confirms the outstanding mineralization strength of TP8 by a unit mass for high amounts of MB dye per unit time. Thus, the present study offers an excellent photocatalyst i.e., TP8 having 8 wt% of PANI for the degradation of MB dye.