Magnetic, self-heating and superhydrophobic sponge for solar-driven high-viscosity oil-water separation

In this work, a novel oil-adsorption sponge with superhydrophobicity was fabricated using polymer-assisted electroless deposition and dip-coating techniques for depositing a rough polydopamine layer, magnetic particles, and low surface energy polydimethylsiloxane onto the surface of a sponge skeleton. The as-prepared superhydrophobic sponge (WCA > 150° and SA < 5°) exhibited rapid adsorption behavior, large adsorption capacity (up to 50.6 times its own dry weight or above 90% of its own volume), excellent durability (above 80% of the adsorption capacity after 80 recycles), and a self-cleaning property owing to sufficient open-cell pores and superelasticity provided by the melamine-formaldehyde host as well as the hierarchical roughness and convenient magnetic recovery enabled by the polymer-assisted electroless deposition approach. The pump-, gravity-, and solar-driven oil-water separation devices based on the fabricated cubic composites were also demonstrated, particularly the separation of high-viscosity oil-water mixtures via the solar-driven mode, demonstrating the broad prospects of such modified sponges in actual applications. This study provides a new avenue for rationally designing novel oil adsorption and separation materials.