Pd₃Co₁ Alloy Nanocluster on the MWCNT Catalyst for Efficient Formic Acid Electro-Oxidation

In this study, the Pd₃Co₁ alloy nanocluster from a multiwalled carbon nanotube (MWCTN) catalyst was fabricated in deep eutectic solvents (DESs) (referred to Pd₃Co₁/CNTs). The catalyst shows a better mass activity towards the formic acid oxidation reaction (FAOR) (2410.1 mA mg_Pd^-1), a better anti-CO toxicity (0.36 V) than Pd/CNTs and commercial Pd/C. The improved performance of Pd₃Co₁/CNTs is attributed to appropriate Co doping, which changed the electronic state around the Pd atom, lowered the d-band of Pd, formed a new Pd-Co bond act at the active sites, affected the adsorption of the toxic intermediates and weakened the dissolution of Pd; moreover, with the assistance of DES, the obtained ultrafine Pd₃Co₁ nanoalloy exposes more active sites to enhance the dehydrogenation process of the FAOR. The study shows a new way to construct a high-performance Pd-alloy catalyst for the direct formic acid fuel cell.