Application of new chitosan 2,4-dihydroxyacetophenone Schiff base @SrFe₁₂O₁₉ nanocomposite for remove of Pb(II) ion...

A new chitosan 2,4-dihydroxyacetophenone Schiff base @SrFe₁₂O₁₉ (Cs-SB@SrFe₁₂O₁₉) nanocomposite was successfully prepared by one-pot reaction and fully characterized for its functional groups, morphology, elemental analysis and thermal behavior by FT-IR, XRD, VSM, DSC, TGA, zeta potential, FE-SEM and EDS techniques. The VSM result showed that Cs-SB@SrFe₁₂O₁₉ has M_s of 11.81 emu/g and H_c of 5488 Oe, known as hard magnetic material. Finally, the as-prepared sample utilized as a new sorbent for the removal of Pb(II) ions from aqueous solution by using batch adsorption experiments. The adsorption of Pb(II) was carried out at different pH, contact time and initial dose of Cs-SB@SrFe₁₂O₁₉. The maximum adsorption capacity was found to be 132 mg/g (99 %) at pH 5 and the contact time of 120 min. Finally, the kinetic studies reveals that the adsorption process of Cs-SB@SrFe₁₂O₁₉ followed by the pseudo second order kinetics model. Also, the sample showed excellent recyclable efficiency up to 5 cycles.