Advanced nanomaterials for highly efficient CO₂ photoreduction and photocatalytic hydrogen evolution

At present, CO₂ photoreduction to value-added chemicals/fuels and photocatalytic hydrogen generation by water splitting are the most promising reactions to fix two main issues simultaneously, rising CO₂ levels and never-lasting energy demand. CO₂, a major contributor to greenhouse gases (GHGs) with about 65% of the total emission, is known to cause adverse effects like global temperature change, ocean acidification, greenhouse effects, etc. The idea of CO₂ capture and its conversion to hydrocarbons can control the further rise of CO₂ levels and help in producing alternative fuels that have several further applications. On the other hand, hydrogen being a zero-emission fuel is considered as a clean and sustainable form of energy that holds great promise for various industrial applications. The current review focuses on the discussion of the recent progress made in designing efficient photocatalytic materials for CO₂ photoreduction and hydrogen evolution reaction (HER). The scope of the current study is limited to the TiO₂ and non-TiO₂ based advanced nanomaterials (i.e. metal chalcogenides, MOFs, carbon nitrides, single-atom catalysts, and low-dimensional nanomaterials). In detail, the influence of important factors that affect the performance of these photocatalysts towards CO₂ photoreduction and HER is reviewed. Special attention is also given in this review to provide a brief account of CO₂ adsorption modes on the catalyst surface and its subsequent reduction pathways/product selectivity. Finally, the review is concluded with additional outlooks regarding upcoming research on promising nanomaterials and reactor design strategies for increasing the efficiency of the photoreactions.