Highly efficient visible light active doped metal oxide photocatalyst and SERS substrate for water treatment

The development of efficient nanomaterials with promising optical and surface properties for multifunctional applications has always been a subject of novel research. In this work, the study of highly efficient TiO₂ nanorods (NRs) and Ta-doped TiO₂ NRs (Ta-TiO₂ NRs) synthesized by alkaline hydrothermal treatment followed by soaking treatment has been reported. NRs were investigated for their potential applications as recyclable/reproducible visible light active photocatalysts and surface-enhanced Raman scattering (SERS) substrates in wastewater treatment. NRs were characterized by various microscopic (scanning and transmission electron microscopy), spectroscopic (X-ray diffraction, X-ray photoelectron, UV-visible, photoluminescence, and Raman spectroscopy), and surface (Brunauer-Emmett-Teller) techniques. The NRs exhibited promising optical properties with a band gap of 2.95 eV (TiO₂ NRs) and 2.58 eV (Ta-TiO₂ NRs) showing excellent photo-degradation activities for methylene blue (MB) dye molecules under natural sunlight. Particularly, Ta-TiO₂ NRs showed enhanced response as visible light active photocatalysts in normal sunlight and also as SERS substrate attributed to the additional defects introduced by Ta doping. It could be explained by the combined effect of doping-induced enhanced visible light absorption and charge transfer (CT) properties of Ta-TiO₂ NRs. Furthermore, Ta-TiO₂ NRs were investigated for their long-term stability, reproducibility of the data, and recyclability in view of their potential applications in water treatment.