Synthesis of green emissive terbium(III) complexes for displays: Optical, electrochemical and photoluminescent...

A series of heteroleptic terbium(III) complexes with fluorinated 2-thenoyltrifluoroacetone (TTFA) and other heteroaromatic units have been synthesized. The developed heteroleptic complexes were inspected via elemental study, cyclic voltammetry, thermal analysis and spectroscopic investigations. Optical band-gap data proposed the conducting property of prepared complexes. The photoluminescence emission profiles illustrated peaks based on terbium(III) cation (Tb³⁺ ) positioned at ~617, 586, 546 and 491 nm, imputed to ⁵ D₄ to ⁷ F_J (J = 3,4,5,6) transitions separately. Most intense peak at 546 nm corresponding to ⁵ D₄  → ⁷ F₅ transition is accountable for the green emissive character of developed complexes. The luminous character of complexes reveals the sensitization of Tb³⁺ by ligands. Color parameters further corroborates the green emanation of Tb³⁺ complexes. The photometric characteristics of complexes recommended their usages in designing display devices.