Aluminoborates as Nonlinear Optical Materials

Ultraviolet (UV) and Deep-UV (DUV, λ<200 nm) nonlinear optical (NLO) materials play a significant role to convert the wavelength of laser for producing UV/DUV coherent light in the laser industry. The Al [Ne]3s² 3p¹ atom with empty d orbitals can form sp³ , sp³ d, and sp³ d² hybrid orbitals when bonding with O/F atoms, which leads to the construction of [AlO_m F_n ] (m+n=4, 5, 6) units. Therein, aluminoborates have received intensive attention due to the effective structural and functional adjustment effects of the diverse Al-O/F units. Accordingly, numerous aluminoborates as candidates for the next generation of UV/DUV NLO materials were discovered. In this review, recently discovered aluminoborates are overviewed and analyzed, including their syntheses, crystal structure features, and second-order NLO performances. We aim to provide the latest progress and outlook on the crystal chemistry of aluminoborates and boost the finding of the next NLO candidates with high performances.