Synthesis, characterization, and application of pristine and clay-templated carbon xerogel microspheres for removing...

Organic xerogel microspheres (SX) were synthesized by inverse emulsion sol-gel polymerization and carbonized to obtain carbon xerogel spheres (SXCs). The catalyst was K₂CO₃ or Fe(C₂H₃O₂)₂, and the clay sodium sepiolite (SNa) or exfoliated vermiculite (V_exf) was added during the synthesis. Depending on the catalyst and clays, the SXCs were designated SXC-K, SXC-Fe, V_exf-K, V_exf-Fe, SNa-Fe, and SNa-K. At pH = 7 and T = 25 °C, the SXCs' adsorption capacities towards diclofenac (DCF) in water increased as follows: SXC-K < V_exf-Fe < SXC-Fe < SNa-Fe < SNa-K < V_exf-K and this order is associated with the SXCs' surface area and mesopore volume. The V_exf-K displayed the highest capacity for DCF due to its optimal textural and chemical properties, and the DCF maximum uptake was 560 mg/g at pH = 6 and T = 35 °C. The adsorption capacity towards Cd²⁺ and Pb²⁺ decreased as SX-K > SX-Fe > SXC-K > SXC-Fe, indicating that the non-carbonized materials (SX) presented higher adsorption capacity than the SXCs because the SXs had a higher acidic site content. Adding SNa or V_exf to SXs enhanced the adsorption capacity towards Cd(II), and SNa-SX-K presented an exceptionally high capacity of 182.7 mg/g. This synergistic effect revealed that the Cd²⁺ was adsorbed on the SX-K acidic sites and by cation exchange on the SNa.