Slippery Shape Memory Tube for Smart Droplet Transportation

Recently, research about controllable droplet transportation in tubes has aroused increased interest. However, existing strategies mainly depend on the elastic tube's shape variation that needs constant external stimuli. Meanwhile, these reported tubes are only suitable for wetting liquids. To achieve the transportation of diverse liquids, different coatings are needed to modify the tube's inner surface to realize complete wetting of different liquids. Herein, we advance a design principle by combining a shape memory polymer (SMP) tube and Nepenthes pitcher plant-inspired slippery surface, which can solve the above-mentioned problems. The SMP offers a tunable tube shape owing to its shape memory effect (SME); the slippery surface reduces the adhesion and expands the applicable range of liquids. Transportation of both water and oils in a wide range of surface tension values can be smartly controlled. The results show that not only the transportation speed and direction can be adjusted but also diverse modes including round-trip transportation, segmented transportation, and antigravity transportation can be achieved. Moreover, applications of the tube in batch inspection of different droplets and step-by-step control of multiple microreactions are also displayed. This work reports a strategy for droplet transportation control based on the tube's SME, which initiates some fresh ideas for designing new superwetting materials toward smart liquid transportation.