ReS₂ with unique trion behavior as a co-catalyst for enhanced sunlight hydrogen production

The interfacial catalytic reaction plays a crucial role in determining hydrogen production efficiency of a photocatalyst. In this work, hollow spherical nano-shell composite (g-C₃N₄/CdS/ReS₂) formed by graphitic carbon nitride (g-C₃N₄), cadmium sulfide (CdS), and rhenium disulfide (ReS₂) was prepared for photocatalytic hydrogen production, with ReS₂ introduced as a relatively inexpensive co-catalyst with excellent performance. It was found that two-electron catalytic reaction took place in this photocatalytic system due to the unique trion behavior of ReS₂ co-catalyst, which greatly enhances the rate of photocatalytic hydrogen production. The tightly bound excitons in the ReS₂ co-catalyst could easily capture the photogenerated electrons in the photocatalytic system to form trions, while g-C₃N₄ in the inner shell and CdS in the middle shell provided sufficient electrons for the formation of trions. The active edge sites of ReS₂ also facilitated the generation and desorption of hydrogen, which creates conditions favoring two-electron catalytic reaction. In addition, oxidation and reduction reactions occurred inside and outside of the hollow spherical nano-shell, respectively, which effectively inhibits the recombination of photogenerated carriers. The unique trion behavior of ReS₂ alters the interfacial catalytic reaction compared to the widely used platinum (Pt) co-catalyst in photocatalytic hydrogen production, which provides a new approach for enhancing the activity of photocatalytic systems.