Metal-oxide-semiconductor resistive gas sensors for fish freshness detection

Fish are prone to spoilage and deterioration during processing, storage, or transportation. Therefore, there is a need for rapid and efficient techniques to detect and evaluate fish freshness during different periods or conditions. Gas sensors are increasingly important in the qualitative and quantitative evaluation of high-protein foods, including fish. Among them, metal-oxide-semiconductor resistive (MOSR) sensors with advantages such as low cost, small size, easy integration, and high sensitivity have been extensively studied in the past few years, which gradually show promising practical application prospects. Herein, we take the detection, classification, and assessment of fish freshness as the actual demand, and summarize the physical and chemical changes of fish during the spoilage process, the volatile marker gases released, and their production mechanisms. Then, we introduce the advantages, performance parameters, and working principles of gas sensors, and summarize the MOSR gas sensors aimed at detecting different kinds of volatile marker gases of fish spoiling in the last 5 years. After that, this paper reviews the research and application progress of MOSR gas sensor arrays and electronic nose technology for various odor indicators and fish freshness detection. Finally, this review points out the multifaceted challenges (sampling system, sensing module, and pattern recognition technology) faced by the rapid detection technology of fish freshness based on metal oxide gas sensors, and the potential solutions and development directions are proposed from the view of multidisciplinary intersection.