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Updated: Aug 16, 2025

Solvothermal Synthesis of MIL-96 and UiO-66-NH2 on Atomic Layer Deposited Metal Oxide Coatings on Fiber Mats
Published on: June 13, 2018
Zn(II)-MOF derived N-doped carbons achieve marked ORR activity in alkaline and acidic media
Feng Chen1, Gao-Yuan Huang1, Ke-An Wang1
1School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China. zhuhaibin@seu.edu.cn.
Abstract:
A highly efficient metal-free N-doped carbon electrocatalyst toward oxygen reduction was obtained by one-pot pyrolysis of a single Zn(II)-MOF with mixed azolate and terephthalate ligands, demonstrating E1/2 of 0.88 V (vs. RHE) in 0.1 M KOH, and 0.79 V (vs. RHE) in 0.5 M H2SO4. It represents one of the best metal-free N-doped carbon electrocatalysts for the acidic ORR.
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