Experimental study on the effect of cold soaking with liquid nitrogen on the coal chemical and microstructural...

In this paper, the chemical microstructure of coal samples is quantitatively analyzed experimentally before and after liquid nitrogen cold soaking, by using elemental analyzer, X-ray diffractometer, and Fourier infrared spectrometer, including the reverse side of chemical composition of elements, organic matter, and functional groups. It was found that with the increase of coal metamorphism, the contents of carbon, nitrogen, and sulfur elements gradually increase, while those of hydrogen and oxygen elements gradually decrease. In addition, as the degree of metamorphism increases, the graphitization phenomenon of coal becomes weaker, the interlayer spacing of aromatic rings (d₀₀₂) increases, the structure of coal crystal nucleus is loose, its order is weakened, the crystal volume becomes smaller, and the void structure unit increases. The FTIR spectra of each coal sample could be divided into four absorption bands, i.e., the aromatic structure, oxygen-containing functional group, aliphatic group, and hydroxyl absorption band. After cold soaking of liquid nitrogen, the peak intensity areas of aromatic and aliphatic structures decrease, while those of oxygenated functional groups and hydroxyl groups increase, and the values of A(C = O)/A(C-O) increase and those of A(CH₃)/A(CH₂) decrease, mainly due to the gradual decrease of methylene side chains and increase of methylene straight chains. The present results are helpful to further reveal the mechanism of adsorption-resolution deformation of coal body due to cold immersion of liquid nitrogen.