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Colloids and Suspensions01:17

Colloids and Suspensions

1.9K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles visible to the naked eye or seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. The suspended particles in a suspension settle out after some time of mixing. The separation of particles from a suspension is...
1.9K
Colloidal precipitates01:09

Colloidal precipitates

708
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
708
Colloids03:22

Colloids

17.7K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
17.7K
Precipitate Formation and Particle Size Control01:16

Precipitate Formation and Particle Size Control

897
In precipitation gravimetry, the precipitating agent should react specifically or selectively with the analyte. While a specific reagent reacts with the analyte alone, a selective reagent can react with a limited number of chemical species.
The obtained precipitate should be either a pure substance of known composition or easily converted to one by a simple process, such as ignition or drying. In addition, the precipitate should be insoluble and easily filterable. In general, filterability...
897
Coagulation01:06

Coagulation

351
Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
351
Centrifugation01:05

Centrifugation

2.4K
Centrifugation is a separation technique based on differences in density or size. It is commonly used to separate solids from aqueous interferents. During centrifugation, the sample is placed in centrifugation tubes and spun at high angular velocity, which allows centrifugal force to act differentially on the different densities or masses of the components. After spinning, the supernatant liquid is decanted. Depending on the specific application, either the pellet or the supernatant is retained...
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Related Experiment Video

Updated: Aug 16, 2025

Visually Based Characterization of the Incipient Particle Motion in Regular Substrates: From Laminar to Turbulent Conditions
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Sedimentation path theory for mass-polydisperse colloidal systems.

Tobias Eckert1, Matthias Schmidt1, Daniel de Las Heras1

  • 1Theoretische Physik II, Physikalisches Institut, Universität Bayreuth, D-95440 Bayreuth, Germany.

The Journal of Chemical Physics
|December 22, 2022
PubMed
Summary
This summary is machine-generated.

This study explores how particle mass variation affects colloidal suspensions under gravity. Mass polydispersity significantly influences sedimentation-diffusion-equilibrium, especially near density matching conditions.

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Area of Science:

  • Colloidal science
  • Soft matter physics
  • Physical chemistry

Background:

  • Colloidal experiments inherently involve polydispersity and gravity.
  • Existing theories primarily address polydispersity's bulk behavior, not gravity's influence on polydisperse systems.

Purpose of the Study:

  • Extend sedimentation path theory to mass-polydisperse colloidal systems.
  • Investigate the interplay between gravity and mass polydispersity in sedimentation-diffusion-equilibrium.
  • Provide a model applicable to various mass distributions, including monodisperse systems.

Main Methods:

  • Utilized sedimentation path theory.
  • Modeled mass-polydisperse colloidal systems with identical particles differing in buoyant mass.
  • Analyzed sedimentation-diffusion-equilibrium.

Main Results:

  • Developed a theoretical model for sedimentation-diffusion-equilibrium in mass-polydisperse colloidal systems.
  • Demonstrated that mass polydispersity strongly impacts systems near density matching.
  • Applied the theory to study crystallization in polydisperse hard sphere suspensions.

Conclusions:

  • The extended theory effectively models gravity's effect on polydisperse colloidal suspensions.
  • Mass polydispersity is a critical factor in sedimentation behavior, particularly under density-matched conditions.
  • The framework is versatile for analyzing both polydisperse and monodisperse colloidal sedimentation.