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Electrospun Conducting Polymers: Approaches and Applications
Mariana Acosta1, Marvin D Santiago2, Jennifer A Irvin1,2
1Materials Science, Engineering and Commercialization Program, Texas State University, San Marcos, TX 78666, USA.
Materials (Basel, Switzerland)
|December 23, 2022
Summary
Conductive polymer (CP) nanofibers offer diverse applications, but their electrospinning is challenging. This review examines methods to overcome these challenges for advanced materials development.
Area of Science:
- Materials Science
- Polymer Chemistry
- Nanotechnology
Background:
- Inherently conductive polymers (CPs) exhibit tunable properties based on oxidation states, enabling applications in electronics and medicine.
- Developing CP nanofibers is crucial for advanced applications like water purification, sensors, and energy storage due to their high surface area and porosity.
Purpose of the Study:
- To review and analyze various methods for electrospinning conductive polymer nanofibers.
- To discuss the advantages and disadvantages of different fabrication techniques.
- To explore the diverse applications of CP nanofibers in sensing, biomedical fields, and energy devices.
Main Methods:
- Exploration of common workarounds for electrospinning CPs, including co-extrusion with carrier polymers, coaxial electrospinning, and coating techniques.
- Analysis of the benefits and drawbacks associated with each fabrication method.
- Review of existing literature on CP nanofiber applications.
Main Results:
- Standard electrospinning is difficult for most CPs due to low molecular weight and rigid structures, often resulting in nanoparticles instead of nanofibers.
- Successful fabrication of CP nanofibers can be achieved through strategies like blending with insulating polymers or using coaxial/coating methods.
- These methods enable the creation of high-surface-area materials suitable for various technological uses.
Conclusions:
- Overcoming the challenges in electrospinning conductive polymers is key to unlocking their full potential in nanotechnology.
- Various innovative techniques allow for the production of CP nanofibers, expanding their applicability.
- CP nanofibers are promising for a wide range of applications, from biomedical devices to energy storage solutions.

