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Preparation of a Crosslinked Poly(imide-siloxane) for Application to Transistor Insulation
Hyeong-Joo Park1, Ju-Young Choi1, Seung-Won Jin1
1Department of Chemistry, Yonsei University, Wonju 26493, Republic of Korea.
Polymers
|December 23, 2022
Summary
A new poly(imide-siloxane) (PIS) material offers enhanced thermal stability and low thermal conductivity for Insulated Gate Bipolar Transistor (IGBT) modules. This advanced insulating material addresses the increasing demands for higher power density and improved heat resistance in electronic devices.
Area of Science:
- Materials Science
- Electrical Engineering
- Polymer Chemistry
Background:
- Insulated Gate Bipolar Transistors (IGBTs) are critical power devices in semiconductor applications.
- Current IGBT modules utilize silicone gel as an insulating layer, which faces limitations with increasing power density and operating temperatures.
- The electronic industry trend towards higher power density necessitates advanced insulating materials with superior thermal stability and insulation performance.
Purpose of the Study:
- To synthesize a novel insulating material for IGBT modules.
- To enhance thermal stability and reduce thermal conductivity compared to existing materials.
- To evaluate the suitability of the new material for demanding electronic applications.
Main Methods:
- Synthesis of poly(imide-siloxane) (PIS).
- Crosslinking of PIS via a hydrosilylation reaction to form a semi-solid Crosslinked PIS.
- Comprehensive characterization of Crosslinked PIS properties, including thermal decomposition temperature, thermal conductivity, optical transparency, dielectric constant, and rheological properties.
- Comparative analysis against a commercial silicone gel.
Main Results:
- The synthesized Crosslinked PIS demonstrated high thermal stability.
- The material exhibited significantly low thermal conductivity.
- Crosslinked PIS also presented other desirable properties suitable for insulation applications.
Conclusions:
- Crosslinked PIS is a promising candidate for advanced IGBT-insulating materials.
- The material's enhanced thermal stability and low thermal conductivity meet the evolving demands of the electronic device industry.
- This new material could enable higher power density and more severe temperature applications for power electronic devices.

