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Updated: Aug 16, 2025

Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization
Published on: August 6, 2018
New Measurement Resolves Key Astrophysical Fe XVII Oscillator Strength Problem
Steffen Kühn1,2, Charles Cheung3, Natalia S Oreshkina1
1Max-Planck-Institut für Kernphysik, Saupfercheckweg 1, 69117 Heidelberg, Germany.
Decades-old discrepancies in X-ray astronomy regarding iron Fe XVII transitions are resolved. New high-resolution experiments at PETRA III accurately measured iron Fe XVII oscillator strengths, aligning with theoretical predictions.
Area of Science:
- Atomic physics
- X-ray astronomy
- Plasma diagnostics
Background:
- A long-standing issue in X-ray astronomy involves discrepancies between theoretical and observed intensity ratios for two critical Fe XVII transitions (3C and 3D).
- These transitions are vital for accurate plasma diagnostics in astrophysical settings.
- Previous studies were limited by lower resolution and signal-to-noise ratios, hindering precise measurements.
Purpose of the Study:
- To resolve the decades-old mystery of Fe XVII oscillator strengths by performing high-precision measurements.
- To reconcile the disagreement between theoretical models and observational data for Fe XVII 3C and 3D transition intensity ratios.
- To improve the accuracy of plasma diagnostics in X-ray astronomy.
Main Methods:
- Utilized the PETRA III synchrotron facility to achieve a 2.5-fold increase in resolving power and a thousandfold increase in signal-to-noise ratio.
- Accurately modeled Lorentzian wings previously indistinguishable from background noise, correcting biased line-strength estimations.
- Measured individual natural linewidths and oscillator strengths for the 3C and 3D transitions.
Main Results:
- The experimental oscillator-strength ratio R_exp = f_3C/f_3D = 3.51(2) was determined, showing excellent agreement with state-of-the-art theoretical calculations (R_th = 3.55(2)).
- Individual measurements of natural linewidths and oscillator strengths for both transitions also align well with theoretical predictions.
- The previously observed discrepancies are attributed to unmodeled Lorentzian wings in earlier analyses.
Conclusions:
- This study successfully resolves the long-standing mystery of Fe XVII oscillator strengths in X-ray astronomy.
- The findings provide accurate data crucial for advancing plasma diagnostics and astrophysical modeling.
- High-precision experimental techniques are essential for validating theoretical models in atomic physics and astrophysics.
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