Effect of Cuprous Oxide Nanocubes and Antimony Nanorods on the Performance of Silicon Nanowire-Based...

Antimony nanorods (SbNRs) anchored to vertically aligned SiNWs serve as cosensitizers and enhance the light absorption of NWs, and their favorably positioned valence band (VB) coupled with their p-type semiconducting nature allows fast hole extraction from SiNWs. Photocorrosion of SiNWs is effectively prevented by a monolayer of N-[3-(trimethoxysilyl)propyl]aniline (TMSPA). Upon assembling a quasi-solid-state solar cell with a SbNRs@TMSPA@SiNW photoanode, a triiodide-iodide (I₃ ^-/I^-) redox couple-based gel encompassing dispersed p-type cuprous oxide nanocubes (Cu₂O NCs) as the hole transport material. and an electrocatalytic NiO as the counter electrode, a power conversion efficiency (PCE) of 4.7% (under 1 sun) is achieved, which is greater by 177% relative to an analogous cell devoid of the Cu₂O NCs and SbNRs. SbNRs at the photoanode maximize charge separation and suppress electron-hole and electron-I₃ ^- recombination at the photoanode/electrolyte interface, thereby improving the overall current collection efficiency. Concurrently, the Cu₂O NCs facilitate hole scavenging from SbNRs or SiNWs and relay them rapidly to the I^- ions in the electrolyte. Optically transparent and mesoporous NiO with a VB conducive to accepting electrons from FTO permits abundant interaction with I₃ ^- ions. The high PCE is a cumulative outcome of the synergistic attributes of SbNRs, Cu₂O NCs, and NiO. The SbNRs@TMSPA@SiNWs/Cu₂O-gel/NiO solar cell also exhibits a noteworthy operational stability, for it endures 500 h of continuous 1 sun illumination accompanied by an ∼24.4% drop in its PCE. The solar cell architecture in view of the judiciously chosen components with favorable energy level offsets, semiconducting/photoactive properties, and remarkable stability opens up pathways to adapt these materials to other solar cells as well.