Sorting of heterogeneous colloids by AC-dielectrophoretic forces in a microfluidic chip with asymmetric orifices

The synthesis of compositionally heterogeneous particles is central to the development of complex colloidal units for self-assembly and self-propulsion. Yet, as the complexity of particles grows, synthesis becomes more prone to "errors". We hypothesize that alternating-current dielectrophoretic forces can efficiently sort Janus particles, as a function of patch size and material, and colloidal dumbbells by size.

We prepared Janus particles with different patch size and material by physical vapor deposition and colloidal dumbbells via capillarity-assisted particle assembly. We then performed sorting experiments in a microfluidic chip comprising electrodes with asymmetric orifices, specifically exploiting the dielectric contrast between different portions of the particles or their size difference to steer them towards different outlets.

We calculated that the DEP force for Janus particles may switch from positive to negative as a function of composition at a critical AC frequency, thus enabling sorting different particles crossing the electrodes' region. The predictions are confirmed by optical microscopy experiments. We also show that intact and "broken" dumbbells can be simply separated as they experience different DEP forces. The integration of multiple asymmetric orifices leads a larger zone with high field gradient to increase separation efficiency and makes it a promising tool to select precise particle populations, isolating fractions with narrowly distributed characteristics.